Speciation of Chromium in Seawater by ICP-AES with Dual Mini-columns Containing Chelating Resin

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Speciation of chromium in seawater by ICP-AES with dual mini-columns containing chelating resin.

A method for the preconcentration and speciation of chromium in seawater was developed. On-line preconcentration and determination were carried out by using inductively coupled plasma atomic emission spectrometry (ICP-AES) with dual mini-columns containing a chelating resin. In this system, Cr(III) was collected on the first column. The effluent containing residual chromium from the first colum...

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On-line preconcentration system using mini-column packed with a chelating resin for the characterization of seasonal variations of trace elements in seawater by ICP-MS and ICP-AES.

An on-line column preconcentration technique coupled with inductively coupled plasma-mass spectrometry (ICP-MS) and -atomic emission spectrometry (ICP-AES) was developed using a mini-column (ca. 3 mm i.d., 40 mm length), that was packed with chelating resin (0.2 g) of iminodiacetic acid groups, Muromac A-1. After the preconcentration step, the column was washed with ammonium acetate buffer (pH ...

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Chromium Speciation in Water by HPLC/ICP-MS

Chromium exists primarily in two forms: trivalent and hexavalent. Trivalent chromium is present in the cationic form as Cr+3 and is an essential nutrient, but hexavalent chromium is toxic and exists as an anion, either as chromate (CrO4 -2) or dichromate (Cr2O7 -2). Therefore, the analysis of total chromium does not always provide a true indication of the effects of chromium present in a sample...

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pre-concentration and determination of platinum (iv) in water samples using chelating resin by inductively coupled plasma atomic emission spectroscopy (icp-aes)

a chelating resin is prepared by condensation polymerization of aniline with formaldehyde andcharacterized by ft-ir, elemental analysis and studied for the preconcentration and determination of traceplatinum ion from environmental water sample using inductively coupled plasma-atomic emission spectroscopy(icp-aes). the optimum ph value for sorption of the metal ions was 5. the maximum adsorption...

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ژورنال

عنوان ژورنال: Analytical Sciences

سال: 2006

ISSN: 0910-6340,1348-2246

DOI: 10.2116/analsci.22.161